n_Fe = 11.2/56 = 0.2 (mol) 

Fe + H2SO4 => FeSO4 + H2 

0.2____0.2_______0.2___0.2 

mH2SO4 = 0.2*98 = 19.6 (g) 

mdd H2SO4 = 19.6*100/10 = 196 (g) 

m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g) 

mFeSO4 = 0.2*152 = 30.4 (g) 

C% FeSO4 = 30.4/206.8 * 100% = 14.7% 

Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml) 

CM FeSO4 = 0.2 / 0.1719 = 1.16 M 

a)

$Fe + H_2SO_4 \to FeSO_4 + H_2$

b) $n_{Fe} = \dfrac{14}{56} = 0,25(mol)$
Theo PTHH : $n_{H_2SO_4} = n_{Fe} =  0,25(mol)$

$\Rightarrow m_{dd\ H_2SO_4} = \dfrac{0,25.98}{10\%} = 245(gam)$

c)

$n_{H_2} = n_{Fe} = 0,25(mol)$

Sau phản ứng, $m_{dd} = 14 + 245 - 0,25.2 = 258,5(gam)$

$C\%_{FeSO_4} = \dfrac{0,25.152}{258,5}.100\% = 14,7\%$

PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,2\cdot56=11,2\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=156,8\left(g\right)\) \(\Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{156,8}\cdot100\%\approx16,2\%\)

a) \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)

PTHH: Mg + H₂SO₄ --> MgSO₄ + H₂

           0,1---->0,1------->0,1---->0,1

=> \(m_{dd.H_2SO_4}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)

b) m_{dd sau pư} = 2,4 + 200 - 0,1.2 = 202,2 (g)

m_MgSO4 = 0,1.120 = 12 (g)

\(C\%_{MgSO_4}=\dfrac{12}{202,2}.100\%=5,9\%\)

c) 

\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

Xét tỉ lệ: \(\dfrac{0,25}{1}>\dfrac{0,1}{1}\) => Hiệu suất tính theo H₂

\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

                      0,05<-----0,05

=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)

a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)

PTHH: Mg + H₂SO₄ ---> MgSO₄ + H₂

           0,1--->0,1---------->0,1-------->0,1

\(m_{dd\left(H_2SO_4\right)}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)

b, \(m_{dd\left(sau.pư\right)}=2,4+200-0,2.2=202,2\left(g\right)\)

\(\rightarrow C\%_{MgSO_4}=\dfrac{0,1.120}{202,2}.100\%=5,93\%\)

c, \(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

LTL: 0,25 > 0,1 => CuO dư

\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)

Theo pt: \(n_{H_2}=n_{Cu}=0,05\left(mol\right)\)

=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)

\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)

\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)

`Fe + H_2 SO_4 -> FeSO_4 + H_2`

`0,2`         `0,2`                `0,2`     `0,2`      `(mol)`

`n_[Fe] = [ 11,2 ] / 56 = 0,2 (mol)`

`a) V_[H_2] = 0,2 . 22,4 = 4,48 (l)`

`b) m_[dd HCl] = [ 0,2 . 98 ] / [ 9,8 ] . 100 = 200 (g)`

`c) C%_[FeSO_4] = [ 0,2 . 152 ] / [ 11,2 + 200 - 0,2 . 2 ] . 100 ~~ 14,42%`

\(a)n_{Zn}=\dfrac{9,1}{65}=0,14mol\\ Zn+CuSO_4\rightarrow Cu+ZnSO_4\\ n_{Cu}=n_{CuSO_4}=n_{Zn}=0,14mol\\ m_{Cu}=0,14.64=8,96g\\ b)m_{CuSO_4}=0,14.160=22,4g\\ m_{ddCuSO_4}=\dfrac{22,4}{20\%}\cdot100\%=112g\\ V_{ddCuSO_4}=\dfrac{112}{1,12}=100ml\)